Ar-matrix stabilization and ir spectra of 1, 1-dimethyl-1-silaethylene and its deuteromethyl derivative

OM Nefedov, AK Maltsev, VN Khabashesku…

文献索引：Nefedov, O. M.; Maltsev, A. K.; Khabashesku, V. N.; Korolev, V. A. Journal of Organometallic Chemistry, 1980 , vol. 201, # 1 p. 123 - 136

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被引用次数: 32

摘要

Abstract The IR spectra of the unstable silaethylenes (CH 3) 2 Si CH 2 and (CD 3) 2 Si CH2 formed in the gas phase from monosilacyclobutanes have been recorded in an argon matrix at 10 K. An assignment of the spectral bands to the unstable species is established by experiments with pyrolysis at higher temperatures and pressures or with a controlled warm- up of the matrix, and also by recording spectra of the same species produced from various ...