Monooxygenase-like oxidation of hydrocarbons by hydrogen peroxide catalyzed by manganese porphyrins and imidazole: selection of the best catalytic system and …

…, JP Renaud, JF Bartoli, M Reina-Artiles…

文献索引：Battioni, P.; Renaud, J. P..; Bartoli, J. F.; Reina-Artiles, M.; Fort, M.; Mansuy, D. Journal of the American Chemical Society, 1988 , vol. 110, # 25 p. 8462 - 8470

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被引用次数: 447

摘要

Abstract: Fe and Mn porphyrins alone are almost unable to catalyze cyclooctene epoxidation or cyclooctane hydroxylation by H202. In the presence of imidazole, Mn (II1) porphyrins, and particularly Mn (TDCPP) CI, are much better catalysts than Fe porphyrins for oxygen-atom transfer from H202 to hydrocarbons. From a study of various Mn porphyrin catalysts and nitrogen base cocatalysts, the most efficient system that has been selected involves Mn ( ...

4680-24-4

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