Interaction of a chirally functionalised porphyrin derivative with chiral micellar aggregates. Construction of a system with stereoselective cytochrome-P450 biomimetic …

…, M Venanzi, C Bombelli, F Ceccacci, G Mancini

文献索引：Cantonetti, Veronica; Monti, Donato; Venanzi, Mariano; Bombelli, Cecilia; Ceccacci, Francesca; Mancini, Giovanna Tetrahedron Asymmetry, 2004 , vol. 15, # 13 p. 1969 - 1977

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被引用次数: 19

摘要

The inclusion behaviour of porphyrin derivative manganese [5-(4-(carboxyphenyl-(Nl- proline)))-10-15-20-triphenylporphyrinyl] chloride 1MnCl in micellar aggregates of sodium N- dodecanoyl-l-prolinate L-SDP and of sodium dodecylsulfate SDS has been studied by means of several spectroscopic techniques. The catalytic activity in the epoxidation reaction of some test chiral olefins has been also investigated. Comparison with the case of the ...