Interaction of a chirally functionalised porphyrin derivative with chiral micellar aggregates. Construction of a system with stereoselective cytochrome-P450 biomimetic …

…, M Venanzi, C Bombelli, F Ceccacci, G Mancini

Index: Cantonetti, Veronica; Monti, Donato; Venanzi, Mariano; Bombelli, Cecilia; Ceccacci, Francesca; Mancini, Giovanna Tetrahedron Asymmetry, 2004 , vol. 15, # 13 p. 1969 - 1977

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Citation Number: 19

Abstract

The inclusion behaviour of porphyrin derivative manganese [5-(4-(carboxyphenyl-(Nl- proline)))-10-15-20-triphenylporphyrinyl] chloride 1MnCl in micellar aggregates of sodium N- dodecanoyl-l-prolinate L-SDP and of sodium dodecylsulfate SDS has been studied by means of several spectroscopic techniques. The catalytic activity in the epoxidation reaction of some test chiral olefins has been also investigated. Comparison with the case of the ...

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