Journal of the American Chemical Society

Stereospecific cross-coupling of vinyl halides with vinyl tin reagents catalyzed by palladium

JK Stille, BL Groh

文献索引：Stille,J.K.; Groh,B.L. Journal of the American Chemical Society, 1987 , vol. 109, p. 813

全文：HTML全文

被引用次数: 432

摘要

Abstract: The palladium-catalyzed cross-coupling reaction of (E)-or (Z)-vinyl iodides with (E)- or (Z)-vinylstannanes gives good yields of stereoisomerically pure unsymmetrical dienes with the same double bond geometry as present in the coupling partners. The reaction takes place at ambient temperature in dimethylformamide in the presence of 1-2% bis (acetonitri1e) dichloropalladium. Because this reaction is tolerant of a variety of ...