Syntheses of (Z, E)-5, 7-dodecadienol and (E, Z)-10, 12-hexadecadienol, Lepidoptera pheromone components, via zinc reduction of enyne precursors. Test of …

…, YN Baranchikov, VM Pet'ko, VC Mastro…

文献索引：Khrimian, Ashot; Klun, Jerome A.; Hijji, Yousef; Baranchikov, Yuri N.; Pet'Ko, Vladimir M.; Mastro, Victor C.; Kramer, Matthew H. Journal of Agricultural and Food Chemistry, 2002 , vol. 50, # 22 p. 6366 - 6370

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被引用次数: 22

摘要

Efficient syntheses of (Z, E)-5, 7-dodecadienol, a pheromone component of the Siberian moth, Dendrolimus superans sibiricus, and (E, Z)-10, 12-hexadecadienol, a pheromone component of various Lepidoptera pheromones, were accomplished by cis reduction of the corresponding enynols with activated zinc. The most energetic reagent was zinc galvanized with copper and silver (Zn/Cu/Ag) that achieved rapid and high-yield reduction in ...