Synthesis

β-Oxo Amides: Inexpensive and Efficient Ligands for the Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction

…, YH Zhang, RJ Song, YX Xie, CL Deng, Y Liang

文献索引：Li, Jin-Heng; Zhang, Yue-Hua; Song, Ren-Jie; Xie, Ye-Xiang; Deng, Chen-Liang; Liang, Yun Synthesis, 2007 , # 19 p. 2957 - 2966

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被引用次数: 8

摘要

Abstract β-Oxo amides were found to be inexpensive and efficient ligands for the palladium- catalyzed Suzuki-Miyaura cross-coupling reaction. In the presence of palladium (II) acetate and N-(4-methoxyphenyl)-3-oxobutanamide (L7), a variety of aryl halides, including deactivated aryl chlorides and heteroaryl halides, were successfully coupled to arylboronic acids in moderate to excellent yields providing very high turnover numbers (maximum ...