前往化源商城

Triphenyltin chloride as a new source of phenyl group for C-heteroatom and C–C bond formation

N Iranpoor, H Firouzabadi, EE Davan, A Rostami…

文献索引:Iranpoor, Nasser; Firouzabadi, Habib; Davan, Elham Etemadi; Rostami, Abed; Nematollahi, Arash Journal of Organometallic Chemistry, 2013 , vol. 740, p. 123 - 130

全文:HTML全文

被引用次数: 11

摘要

Ph3SnCl is introduced as a very suitable source of phenyl group for coupling with phenols, amines, and thiols in the presence of Cu (OAc) 2 in Et3N at room temperature to give aryl ethers, amines, and arylthio ethers in high yields. In addition, the application of Ph3SnCl in the Stille coupling of aryl halides in the presence of Pd (0) catalyst in PEG 400 at 110° C is discussed.

 相关合成线路

~83%

~67%

~82%

~60%

~81%

~73%

~74%

~86%

~84%

~73%

~90%

~86%

~87%

~87%

~78%

~93%

~84%

~63%

~61%

~66%

~80%

~82%

~89%

~58%

~78%

~75%

~65%

~84%

~85%

~79%

~90%

~78%

~77%