Tetrahedron

Potassium permanganate/carboxylic acid/organic solvent: a powerful reagent for enone oxidation and aryl coupling reactions

AS Demir, H Findik

文献索引：Demir, Ayhan S.; Findik, Hamide Tetrahedron, 2008 , vol. 64, # 27 p. 6196 - 6201

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被引用次数: 35

摘要

The α′-acetoxylation of enones and the α-acetoxylation of aromatic ketones were carried out with potassium permanganate and acetic acid, in which acetoxylation products were obtained in 74–96% yields. The same reaction was carried out with carboxylic acids other than acetic acid, which furnished corresponding acyloxy ketones with the same regioselectivity. For the first time, formyloxylation products were synthesized in a 61–85% ...