Journal of Organometallic Chemistry

Elektrochemische synthese metallorganischer verbindungen: V. Das verhalten von cyclooctatetraen bei der elektrochemischen reduktion in tetrahydrofuran

H Lehmkuhl, S Kintopf

文献索引：Lehmkuhl,H. et al. Journal of Organometallic Chemistry, 1973 , vol. 56, p. 41 - 52

全文：HTML全文

被引用次数: 18

摘要

Abstract The ion pairs [R 4 El]+[COT]− and [R 4 El]+ 2 [COT] 2−(El= N, P) are observed as intermediates in the electrochemical reduction of cyclooctatetraene in the presence of tetraorganoonium cations. The preparation of these ion pairs has been examined, and their reactions in THF have been followed by polarography and cyclic voltammetry and the reaction products isolated and identified.