Chemische Berichte

Use of Magnesium Anthracene· 3THF in Synthesis: Generation of Grignard Compounds and Other Reactions with Organic Halides

B Bogdanovic̀, N Janke, HG Kinzelmann

文献索引：Bogdanovic, Borislav; Janke, Nikolaus; Kinzelmann, Hans-Georg Chemische Berichte, 1990 , vol. 123, # 7 p. 1507 - 1515

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被引用次数: 17

摘要

The course (a),(b),(c)(Scheme 1) of the reaction of magnesium anthracene. 3 THF (1) with organic halides (RX) is dependent on the nature of RX. With alkyl halides in THF 1 reacts as a nucleophile, whereby primary as well as secondary alkyl hal-ides produce dialkyldihydroanthracenes (4-4") and tertiary alkyl halides yield primarily monoalkyl- substituted dihydroanthracenes (2, 2'). With bromo-and iodobenzene in THF 1 reacts ...