Journal of the American Chemical Society

Formation of mono-and dianions of polycyclic hydrocarbons through deprotonation with the alkylithium-N, N, N', N'-tetramethylethylenediamine complex. Convenient …

RG Harvey, H Cho

文献索引：Harvey,R.G.; Cho,H. Journal of the American Chemical Society, 1974 , vol. 96, p. 2434 - 2441

被引用次数: 41

摘要

Abstract: Interaction of 9, lO-dihydroanthracene and its 9-and 10-methyl and ethyl derivatives (la-f) with n-butyllithium in cyclohexane and excess N, N, N', N '- tetramethylethylenediamine afforded the respective dianionic intermediates. The latter on treatment with cadmium (I1) chloride or other metal salts underwent transformation to fully aromatic hydrocarbons in essentially quantitative yield. The presence of a secondary or ...

Bulletin codicologique

[Cognacq,J.-C. et al. Bulletin de la Societe Chimique de France, 1967 , p. 1190 - 1196]

Nitration of 9, 10-Dimethylanthracene and 9, 10-Diethylanthr...

[Suzuki,H. et al. Bulletin of the Chemical Society of Japan, 1974 , vol. 47, p. 3106 - 3108]

Bulletin codicologique

[Cognacq,J.-C. et al. Bulletin de la Societe Chimique de France, 1967 , p. 1190 - 1196]

Stereoelectronic effects in the deprotonation of arylalkyl r...

[Tolbert, Laren M.; Khanna, Rajive K.; Popp, Ann E.; Gelbaum, Leslie; Bottomley, Lawrence A. Journal of the American Chemical Society, 1990 , vol. 112, # 6 p. 2373 - 2378]

Syntheses of 9, 10-disubstituted anthracenes derived from 9,...

[Duerr, Brook F.; Chung, Y.-S.; Czarnik, Anthony W. Journal of Organic Chemistry, 1988 , vol. 53, # 9 p. 2120 - 2122]