Syntheses of 9, 10-disubstituted anthracenes derived from 9, 10-dilithioanthracene

BF Duerr, YS Chung, AW Czarnik

文献索引：Duerr, Brook F.; Chung, Y.-S.; Czarnik, Anthony W. Journal of Organic Chemistry, 1988 , vol. 53, # 9 p. 2120 - 2122

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被引用次数: 57

摘要

105-106" C) in 51 and 38%, respectively. Not surprisingly, attempted reactions with isopropyl and tert-butyl halides afforded only anthracene itself after aqueous workup. Quenching of 9, lO-dilithioanthracene with CO, has been reported previously to provide the corresponding dicarboxylic acid., Conversion to the diacid chloride with SOCl, and workup with methanol afforded 9, lO-dicarbomethoxyanthracene (2c), made previously by ...