Transition??Metal??Catalyzed Sequential Cross??Coupling of Bis (iodozincio) methane and??ethane with Two Different Organic Halides

…, M Kobata, K Ukai, K Oshima, K Utimoto…

文献索引：Yoshino, Hideaki; Toda, Narihiro; Kobata, Masami; Ukai, Katsumi; Oshima, Koichiro; Utimoto, Kiitiro; Matsubara, Seijiro Chemistry - A European Journal, 2006 , vol. 12, # 3 p. 721 - 726

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被引用次数: 20

摘要

Abstract Bis (iodozincio) methane, prepared from diiodomethane and zinc, reacts with an organic halide in the presence of a transition-metal catalyst to give an iodozinciomethylenated compound; this then reacts with another organic halide to form a C [BOND] C bond. The overall process connects two electrophiles with one carbon atom. Bis (iodozincio) ethane can also undergo this transformation, yielding a new stereogenic ...