Addition Polymerization Catalyzed by Substituted Acyl Peroxides

CC Price, RW Kell, E Krebs

文献索引：Price; Kell; Krebs Journal of the American Chemical Society, 1942 , vol. 64, p. 1103,1104

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被引用次数: 34

摘要

R'+ CHa:: CHX+ R: CHa: CHX'---t R (CH&HX) DCHzCHX'The nature of various processes which might initiate such a chain reaction has been a matter of considerable~ peculation. 2~~ Schulz and Wittig have shown, however, that the free radicals formed from dissociation of tetraphenylsu~ cinonitrile~ or froin the decomposition of benzene azotriphenylmethane (CsH5N= NC (CaH~)@ are capable of catalyzing the polymerization of styrene.