Highly Efficient Alkane Oxidation Catalyzed by [MnV (N)(CN) 4] 2–. Evidence for [MnVII (N)(O)(CN) 4] 2–as an Active Intermediate

…, WL Man, HK Kwong, WWY Lam, G Chen…

文献索引：Ma, Li; Pan, Yi; Man, Wai-Lun; Kwong, Hoi-Ki; Lam, William W.Y.; Chen, Gui; Lau, Kai-Chung; Lau, Tai-Chu Journal of the American Chemical Society, 2014 , vol. 136, # 21 p. 7680 - 7687

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被引用次数: 14

摘要

The oxidation of various alkanes catalyzed by [MnV (N)(CN) 4] 2–using various terminal oxidants at room temperature has been investigated. Excellent yields of alcohols and ketones (> 95%) are obtained using H2O2 as oxidant and CF3CH2OH as solvent. Good yields (> 80%) are also obtained using (NH4) 2 [Ce (NO3) 6] in CF3CH2OH/H2O. Kinetic isotope effects (KIEs) are determined by using an equimolar mixture of cyclohexane (c- ...