Fluoride salts on alumina as reagents for alkylation of phenols and alcohols.

…, J Yamawaki, T Kawate, S Sumi, T Hanafusa

文献索引：ANDO; YAMAWAKI; KAWATE; SUMI; HANAFUSA 1982 , vol. V 55, # N 8 p. 2504 - 2507

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被引用次数: 134

摘要

The effectiveness of alkali metal fluorides impregnated on alumina as a reagent for promoting alkylation was optimized with respect to the metal cation, the amount of impregnation, and the reaction solvent. Potassium or caesium fluoride on alumina in acetonitrile or 1, 2-dimethoxyethane was concluded to be the best reaction system for general use. O-Alkylation of substituted phenols, primary and secondary alcohols, and a ...