Deoxygenative Dimerization of Benzylic and Allylic Alcohols, and Their Ethers and Esters Using Lanthanum Metal and Chlorotrimethylsilane in the Presence of a …

T Nishino, Y Nishiyama, N Sonoda

文献索引：Nishino, Toshiki; Nishiyama, Yutaka; Sonoda, Noboru Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 3 p. 635 - 641

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被引用次数: 11

摘要

Benzylic and allylic alcohols were deoxygenatively dimerized by a treatment with lanthanum metal and chlorotrimethylsilane in the presence of a catalytic amount of iodine, giving the corresponding coupling products, alkanes, in moderate-to-good yields. This dimerization reaction was dramatically accelerated by the addition of a catalytic amount of copper (I) iodide. Similarly, ethers and esters were deoxygenatively dimerized by La/Me 3 SiCl/cat. I ...