The Journal of Organic Chemistry

Oxidation of Benzyltrialkylstannanes by Iodosylbenzene Catalyzed by Iron Tetrakis (pentafluorophenyl) porphyrin Chloride. Possible Role of Benzyloxy Radicals

E Baciocchi, M Ioele

文献索引：Baciocchi, Enrico; Ioele, Marcella Journal of Organic Chemistry, 1995 , vol. 60, # 17 p. 5504 - 5508

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被引用次数: 4

摘要

Results The reactions have been carried out, either in dichloromethane or in benzene, at 25 “C, under rigorous exclusion of oxygen (freeze-pump-thaw method), using a 20: 20: 1 substrate-iodosylbenzene-iron porphyrin molar ratio. Some experiments have also been carried out in CDzClz and in a mixed solvent (80: 18: 2CHzC12-MeOH-HZO), hereafter simply indicated as the mixed solvent. After the usual workup (see Experimental Section), ...