Mechanisms for the removal of benzyl protecting groups in synthetic peptides by trifluoromethanesulfonic acid-trifluoroacetic acid-dimethyl sulfide

JP Tam, WF Heath, RB Merrifield

文献索引：Journal of the American Chemical Society, , vol. 108, # 17 p. 5242 - 5251

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被引用次数: 163

摘要

... 0 1986 American Chemical Society ... Initial and average rate constants sl) were measured at fixed concentrations of DMS (from 0 to 50% by vol) as the concentration of TFMSA was varied from 0 to the highest point experimentally possible, with the remaining volume made up ...