Atmospheric chemistry of C 2 F 5 CHO: mechanism of the C 2 F 5 C (O) O 2+ HO 2 reaction

MPS Andersen, MD Hurley, TJ Wallington, JC Ball…

文献索引：Andersen, M. P. Sulbaek; Hurley, M. D.; Wallington, T. J.; Ball, J. C.; Martin, J. W.; Ellis, D. A.; Mabury, S. A. Chemical Physics Letters, 2003 , vol. 381, # 1-2 p. 14 - 21

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被引用次数: 32

摘要

Smog chamber/FTIR techniques were used to study the gas-phase reaction of C2F5C (O) O2 with HO2 radicals in 100–700 Torr of air, or O2, diluent at 296 K. The reaction proceeds by two pathways leading to formation of C2F5C (O) OH and O3 in a yield of 24±4% and ...