Atmospheric chemistry of C 2 F 5 CHO: mechanism of the C 2 F 5 C (O) O 2+ HO 2 reaction

MPS Andersen, MD Hurley, TJ Wallington, JC Ball…

Index: Andersen, M. P. Sulbaek; Hurley, M. D.; Wallington, T. J.; Ball, J. C.; Martin, J. W.; Ellis, D. A.; Mabury, S. A. Chemical Physics Letters, 2003 , vol. 381, # 1-2 p. 14 - 21

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Citation Number: 32

Abstract

Smog chamber/FTIR techniques were used to study the gas-phase reaction of C2F5C (O) O2 with HO2 radicals in 100–700 Torr of air, or O2, diluent at 296 K. The reaction proceeds by two pathways leading to formation of C2F5C (O) OH and O3 in a yield of 24±4% and ...