Laser-powered homogeneous and heterogeneous pyrolysis of 2-nitropropane

J Pola, M Farkačová, P Kubát, A Trka

文献索引：Pola, Josef; Farkacova, Marta; Kubat, Pavel; Trka, Antonin Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1984 , vol. 80, p. 1499 - 1506

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被引用次数: 24

摘要

The pyrolysis of 2-nitropropane has been studied under both homogeneous conditions (using a continuous-wave CO2 laser and sensitized by sulphur hexafluoride) and heterogeneous conditions (pulsed pyrolysis) at temperatures in the range 820–1210 K. A comparison of both decompositions is aided by the determination of spatial temperature profiles and the effective temperature in the laser-driven reaction by using calculations of ...