Propylene oxidation by palladium nitro and nitrato complexes: in situ NMR and IR studies
…, AV Golovin, VA Likholobov, EV Gusevskaya
文献索引：Beck, Irene E.; Golovin, Anatoli V.; Likholobov, Vladimir A.; Gusevskaya, Elena V. Journal of Organometallic Chemistry, 2004 , vol. 689, # 18 p. 2880 - 2887
The mechanism of the propylene oxidation by Pd (NOn) Cl2− m (CH3CN) 2 complexes (n= 2, 3; m= 0, 1, 2) in chloroform solutions has been studied by 1H NMR and IR spectroscopy. The main reaction products are acetone and 2-nitropropylene, with their ratio depending on the equilibrium existing in the reaction solutions between palladium complexes containing NOn ligands bonded to a palladium atom via either an oxygen or a nitrogen atom. ...
