A new variant of the synthesis of disparlure via acetylenic intermediates

J Jonas, P Slanina, O Humpa…

文献索引：Jonas, Jaroslav; Slanina, Pavel; Humpa, Otakar; Mazal, Ctibor Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 857 - 859

全文：HTML全文

被引用次数: 1

摘要

Abstract Disparlure, the sexual feromone of the Gypsy Moth, has been prepared via the known intermediate 2-methyl-7-octadecyne, using a new constructional principle: C 9+ C 10→ C 19. The so far undescribed 7-methyl-1-octyne was used as the C 9 component. The advantages of this procedure consist in higher yields of disparlure and in a substantial simplification of the method of purification of 2-methyl-7-octadecyne.