Tetrahedron

Synthesis of Z-isomeric insect sex pheromone components via ethenolysis of 1, 5-cyclooctadiene

VI Bykov, TA Butenko, EB Petrova, ES Finkelshtein

文献索引：Bykov, Victor I.; Butenko, Tamara A.; Petrova, Elena B.; Finkelshtein, Eugene Sh. Tetrahedron, 1999 , vol. 55, # 27 p. 8249 - 8252

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被引用次数: 21

摘要

A novel syntheses of Z-5-decenol, Z-5-decenyl acetate, Z-7-dodecenol, Z-7-dodecenyl acetate, Z-9-tricosene, Z-7, 8-epoxy-2-methyloctadecane which are sex pheromone components of Lepidoptera and Diptera orders, have been realized via stereoselective cometathesis of 1, 5-cyclooctadiene with ethylene in the presence of MoCl5/SiO2-SnMe4 as a key reaction. The main cometathesis product, 1, Z-5, 9-decatriene, has been converted ...