Sulfur and nitrogen mustard carbonate analogues

…, M Chiurato, J Peltier, P Tundo

文献索引：Arico, Fabio; Chiurato, Matteo; Peltier, Josephine; Tundo, Pietro European Journal of Organic Chemistry, 2012 , # 17 p. 3223 - 3228

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被引用次数: 10

摘要

Abstract Sulfur and nitrogen half-mustard compounds lose their aggressive properties when the chlorine atom is replaced by a carbonate moiety. The anchimeric effect of the novel mustard carbonate analogues is investigated. The reaction follows first-order kinetics, does not need any base, and occurs with–OH,–NH and acidic–CH nucleophiles. Most of these molecules are unexplored and might provide a novel strategy for the preparation of ...