A comparative study on the binding behaviors of β-cyclodextrin and its two derivatives to four fanlike organic guests

LX Song, HM Wang, XQ Guo, L Bai

文献索引：Le, Xin Song; Hai, Ming Wang; Xue, Qing Guo; Bai, Lei Journal of Organic Chemistry, 2008 , vol. 73, # 21 p. 8305 - 8316

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被引用次数: 52

摘要

Four fanlike organic compounds, 1-ethoxybenzene (EOB), 1-butoxybenzene (BOB), 1- dodecyloxybenzene (DOB), and 1-(dodecyloxy)-2-methoxybenzene (DOMB), were chosen as guests, and β-cyclodextrin (β-CD) and its two derivatives, mono (2-O-2-methyl)-β-CD and mono (2-O-2-hydroxy-propyl)-β-CD, were chosen as hosts. Energy changes involved in host− guest inclusion processes were clearly obtained by applying semiempirical PM3 ...