The nature of the transition state in amides pyrolysis. The rates of pyrolysis of N??benzoyl and N??acetylpropanamide, N??benzoyl and N??acetyl??2??methylpropanamide, …

NA Al??Awadi, FA Al??Omran…

文献索引：Al-Awadi, Nouria A.; Al-Omran, Fatima A.; Mathew, Tommy International Journal of Chemical Kinetics, 1995 , vol. 27, # 1 p. 1 - 6

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被引用次数: 2

摘要

Abstract The rates of gas-phase elimination reactions of N-benzoyl and N-acetyl- propanamide and N-benzoyl and N-acetyl-2-methylpropanamide are measured and discussed. They undergo unimolecular first-order elimination reactions. The reactivities of N- benzoylamides have been compared with each other and with those of N-acetylamides. The kinetic data together with the product analysis reveals that, the statistical factor of the ...