Journal of the American Chemical Society

The pyrolysis of esters

CD Hurd, FH Blunck

文献索引：Hurd; Blunck Journal of the American Chemical Society, 1938 , vol. 60, p. 2419,2422

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被引用次数: 167

摘要

summary 1. cis-1, 2-Dimethylcyclopentanediol-1, 2 un-dergoes the pinacol rearrangement with migration of a methyl group and production of 2, 2-dimethylcyclopentanone. 2. tvuns-1, 2-Dimethylcyclopentanedioll-1, 2 when boiled with dilute aqueous acid undergoes resinification. It has not been possible to characterize any product from this reaction. It is suggested that dehydration without rearrangement is here occurring, yielding a product ...