Iron??Catalyzed Reduction of Carboxylic Esters to Alcohols

K Junge, B Wendt, S Zhou…

文献索引：Junge, Kathrin; Wendt, Bianca; Zhou, Shaolin; Beller, Matthias European Journal of Organic Chemistry, 2013 , # 11 p. 2061 - 2065

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被引用次数: 18

摘要

Abstract A novel catalytic system formed from Fe (stearate) 2/NH 2 CH 2 CH 2 NH 2 and polymethylhydrosiloxane was directly developed for the hydrosilylation of carboxylic acid esters to alcohols. The catalytic method exhibits broad substrate scope, including 20 aliphatic, aromatic, and heterocyclic esters. The corresponding alcohols are obtained in moderate to very good yields.