The Journal of organic chemistry

A mild protocol for the conversion of simple esters to tert-butyl esters

MG Stanton, MR Gagné

文献索引：Stanton, Matthew G.; Gagne, Michel R. Journal of Organic Chemistry, 1997 , vol. 62, # 23 p. 8240 - 8242

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被引用次数: 63

摘要

The ester functional group is ubiquitous throughout the natural and synthetic world of organic chemistry and has resulted in decades of effort being devoted to its synthesis and manipulation. In addition to being valuable synthetic targets themselves, esters also serve the role of protective groups for other functionalities. Simple esters, however, are problematic in that harsh reaction conditions are normally required for net hydrolysis. To ...