Organic letters

Indium (III) Acetate-Catalyzed Intermolecular Radical Addition of Organic Iodides to Electron-Deficient Alkenes

K Miura, M Tomita, J Ichikawa, A Hosomi

文献索引：Miura, Katsukiyo; Tomita, Mitsuru; Ichikawa, Junji; Hosomi, Akira Organic Letters, 2008 , vol. 10, # 1 p. 133 - 136

全文：HTML全文

被引用次数: 18

摘要

In the presence of phenylsilane and a catalytic amount of indium (III) acetate, organic iodides added to electron-deficient alkenes in ethanol at room temperature. Both simple and functionalized organic iodides were applicable to this reaction. A plausible reaction mechanism involves the formation of indium hydride species by hydride transfer from silicon to indium and an indium hydride-mediated radical chain process.