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Palladium on carbon–bromobenzene mediated esterification and transesterification

SK Aavula, A Chikkulapalli, N Hanumanthappa…

文献索引:Aavula, Sanjeev Kumar; Chikkulapalli, Anil; Hanumanthappa; Jyothi, Indira; Vinod Kumar; Manjunatha, Sulur G. Tetrahedron Letters, 2013 , vol. 54, # 42 p. 5690 - 5694

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被引用次数: 4

摘要

Abstract A series of carboxylic acids were converted into their corresponding esters using the Pd/C catalyzed hydrogenation conditions in the presence of catalytic bromobenzene in alcohols and the method could also be applicable for the transesterification of esters. Good to excellent yields were obtained for different aliphatic or aromatic starting materials. The success of this esterification relies on the in situ generation of hydrobromic acid (HBr) from ...