Déplacements homolytiques intramoléculaires. 19. Stéréochimie de la décomposition induite de peroxydes insaturés conduisant à la formation d'hétérocycles à trois …
…, F Flies, MJ Bourgeois, E Montaudon…
文献索引：Lubeigt, X.; Flies, F.; Bourgeois, M. J.; Montaudon, E.; Maillard, B. Canadian Journal of Chemistry, 1991 , vol. 69, # 8 p. 1320 - 1325
Homolytic decomposition induced by addition of dichloromethyl radicals to β-and γ- unsaturated peroxides having a substituent on the chain linking the unsaturation and the peroxide function was studied. The stereochemistry of the heterocycles produced was determined by I3C NMR and the stereoselectivity of intramolecular homolytic substitution on the peroxidic bond discussed. Key words: unsaturated peroxides, homolytic ...
