Déplacements homolytiques intramoléculaires. 19. Stéréochimie de la décomposition induite de peroxydes insaturés conduisant à la formation d'hétérocycles à trois …

…, F Flies, MJ Bourgeois, E Montaudon…

Index: Lubeigt, X.; Flies, F.; Bourgeois, M. J.; Montaudon, E.; Maillard, B. Canadian Journal of Chemistry, 1991 , vol. 69, # 8 p. 1320 - 1325

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Citation Number: 7

Abstract

Homolytic decomposition induced by addition of dichloromethyl radicals to β-and γ- unsaturated peroxides having a substituent on the chain linking the unsaturation and the peroxide function was studied. The stereochemistry of the heterocycles produced was determined by I3C NMR and the stereoselectivity of intramolecular homolytic substitution on the peroxidic bond discussed. Key words: unsaturated peroxides, homolytic ...