Journal of the American Chemical Society

Ene reaction of singlet oxygen: an entropy-controlled process determines the reaction rate

JR Hurst, GB Schuster

文献索引：Hurst, John R.; Schuster, Gary B. Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6854 - 6856

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被引用次数: 45

摘要

The effect of silyl substitution at carbon on the SN2 reactivity is even more dramatic. The calculated barriers for the sN2 hydride exchange reactions2'5a, 5b, and 5c are 47.4 (44.3), 50.1 (47.4), and 35.9 (35.3) kcalamol-', respectively, at 6-31G*//3-21G (the values in parentheses are at 3-21G//3-21G).