Cobalt-catalyzed direct electrochemical cross-coupling between aryl or heteroaryl halides and allylic acetates or carbonates

P Gomes, C Gosmini, J Périchon

文献索引：Gomes, Paulo; Gosmini, Corinne; Perichon, Jacques Journal of Organic Chemistry, 2003 , vol. 68, # 3 p. 1142 - 1145

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被引用次数: 48

摘要

The electroreduction of a mixture of functionalized aromatic or heteroaromatic bromides or chlorides and allylic compounds such as acetates or carbonates in an electrochemical cell fitted with a sacrificial iron anode affords, in the presence of cobalt halide associated with pyridine as ligand in acetonitrile or DMF, the corresponding coupling product in good yields.

~61%

~48%

~0%

~60%

~57%

~83%

~53%

~55%

~70%

~0%

~66%

~74%

~58%

~29%

~49%

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