Tetrahedron

Synthese et reactivite d'oxycyclopropanes electrophiles

H Abdallah, R Grée, R Carrié

文献索引：Abdallah, Hassan; Gree, Rene; Carrie, Robert Tetrahedron, 1985 , vol. 41, # 19 p. 4339 - 4346

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被引用次数: 19

摘要

“Electrophilic oxycyclopropanes” 4 to 6 have been prepared starting from olefins 7. Ring opening of these cyclopropanes occurs under very smooth conditions (DMSO, room temperature). A push-pull type system is then also a powerful driving force with regard to the CC bond cleavage in cyclopropanes.