Fast and highly chemoselective alkynylation of thiols with hypervalent iodine reagents enabled through a low energy barrier concerted mechanism

R Frei, MD Wodrich, DP Hari, PA Borin…

文献索引：Huang, Hanchu; Zhang, Guojin; Gong, Li; Zhang, Shuaiyan; Chen, Yiyun Journal of the American Chemical Society, 2014 , vol. 136, # 6 p. 2280 - 2283

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被引用次数: 55

摘要

... Journal of the ... 2014, 136 (47), pp 16563–16573. DOI: 10.1021/ja5083014. Publication Date (Web): November 1, 2014. Copyright © 2014 American Chemical Society. ... vinyl benziodoxolone 6 could be observed, although the small quantities of 6 formed did not allow us to isolate ...

~90%

~95%

~91%

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