Tetrahedron

Facile transformation of esters to nitriles

Y Suzuki, K Moriyama, H Togo

文献索引：Suzuki, Yusuke; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2011 , vol. 67, # 41 p. 7956 - 7962

被引用次数: 18

摘要

Various esters were efficiently converted into the corresponding nitriles in good yields by the treatment with sodium diisobutyl-tert-butoxyaluminium hydride (SDBBA-H), followed by treatment with molecular iodine in aq ammonia. The present one-pot method is very efficient and practical for the conversion of various aromatic and aliphatic esters into the corresponding nitriles.

10287-53-3

对-N,N-二甲氨基苯甲酸乙酯

~16%

1197-19-9

4-(二甲胺基)苄腈

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~71%

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~80%

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~46%

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~73%

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~92%

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~88%

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~82%

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~83%

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~78%

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~72%

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~71%

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~82%

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~75%

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~0%

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~13%

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~80%

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~27%

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~80%

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~76%

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~70%

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~72%

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~86%

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~74%

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~84%

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~79%

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~72%

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