Organolanthanide-catalyzed hydroamination. A kinetic, mechanistic, and diastereoselectivity study of the cyclization of N-unprotected amino olefins

MR Gagne, CL Stern, TJ Marks

文献索引：Gagne, Michel R.; Stern, Charlotte L.; Marks, Tobin J. Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 275 - 294

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被引用次数: 446

摘要

The use of early transition metal and f-element complexes to effect synthetically useful organic transformations is rapidly becoming an important interfacial boundary between traditional organometallic and synthetic organic chemistry.'A substantial amount of literature has recently emerged concerning stoichiometric activation of, and CC bond formation involving, synthons such as alkynes,* ben~ ynes,~ alkene^,^ imine^,^ and nitrile^.^ A