Synthesis of aromatic carbonyl compounds via thallation-carbonylation of arenes

RC Larock, CA Fellows

文献索引：Larock, Richard C.; Fellows, Constance A. Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 1900 - 1907

全文：HTML全文

被引用次数: 61

摘要

Abstract: Simple arenes, substituted benzylic and p-phenethyl alcohols, benzoic acid, phenylacetic acid, benzamide, acetanilide, phenylurea, and benzophenone have been thallated under a variety of reaction conditions with thallium (II1) trifluoroacetate and subsequently carbonylated with 10% PdC12, 2 equiv of LiC1, and MgO in either methanol or tetrahydrofuran under 1 atm of carbon monoxide to give aromatic esters, substituted ...