Solvent effects on Diels-Alder reactions. The use of aqueous mixtures of fluorinated alcohols and the study of reactions of acrylonitrile
…, J Gil, RM Martínez, JA Mayoral, L Salvatella…
文献索引：Cativiela, Carlos; Garcia, Jose I.; Gil; Martinez, Rosa M.; Mayoral, Jose A.; Salvatella, Luis; Urieta, Jose S.; Mainar; Abraham, Michael H. Journal of the Chemical Society. Perkin Transactions 2, 1997 , # 3 p. 653 - 660
Rate, endo/exo, regio-and diastereo-facial selectivities of several Diels–Alder reactions were measured in a series of fluorinated alcohol–water mixtures, whose solvophobicity has been determined by means of the solvophobic power (Sp) parameter. Solvophobicity is the main factor influencing the reaction rate, alth
