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Tetrahedron

Recoverable silica-gel supported binam-prolinamides as organocatalysts for the enantioselective solvent-free intra-and intermolecular aldol reaction

A Bañón-Caballero, G Guillena, C Nájera, E Faggi…

文献索引:Banon-Caballero, Abraham; Guillena, Gabriela; Najera, Carmen; Faggi, Enrico; Sebastian, Rosa Maria; Vallribera, Adelina Tetrahedron, 2013 , vol. 69, # 4 p. 1307 - 1315

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被引用次数: 28

摘要

Silica-gel supported binam-derived prolinamides are efficient organocatalysts for the direct intramolecular and intermolecular aldol reaction under solvent-free conditions using conventional magnetic stirring. These organocatalysts in combination with benzoic acid showed similar results to those obtained under similar homogeneous reaction conditions using an organocatalyst of related structure. For the intermolecular process, the aldol ...