Conversions of carbonyl compounds via their polymeric sulfonylhydrazones into alkenes, alkanes, and nitriles

H Kamogawa, A Kanzawa, M Kadoya, T Naito…

文献索引：Kamogawa, Hiroyoshi; Kanzawa, Asami; Kadoya, Masahiro; Naito, Takeshi; Nanasawa, Masato Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 3 p. 762 - 765

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被引用次数: 79

摘要

Reins consisting of cross-linked poly (styrene-divinylbenzene) matrices functionalized with hydrazinosulfonyl groups react with aldehydes and ketones to form the sulfonylhydrazone derivatives. The extent of the reaction is sensitive to the type of resin and the bulk of the carbonyl compound. When heated strongly under alkaline conditions, the sulfonylhydrazones release the corresponding alkenes; upon the NaBH 4 or LiAlH 4 ...