Journal of the Chemical Society, Perkin Transactions 2

Synthesis and stereochemistry of β-aryl-β-haloacroleins: useful intermediates for the preparation of (Z) and (E)-2-en-4-ynecarbaldehydes and for the synthesis of …

AMS Silva

文献索引：Prim, Damien; Fuss, Alexia; Kirsch, Gilbert; Silva, Artur M. S. Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 6 p. 1175 - 1180

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被引用次数: 30

摘要

The synthesis of α-substituted β-aryl-β-haloacroleins by two different pathways is presented. The determination of their stereochemistry by NOE experiments is reported for the first time. Furthermore, we describe the preparation of 2-en-4-ynecarbaldehydes and access to rubrolide derivatives from β-aryl-β-haloacroleins.