The Journal of Organic Chemistry

Hydroboration. 57. Hydroboration with 9-borabicyclo [3.3. 1] nonane of alkenes containing representative functional groups

HC Brown, J Chen

文献索引：Brown, Herbert C.; Chen, Jackson C. Journal of Organic Chemistry, 1981 , vol. 46, # 20 p. 3978 - 3988

被引用次数: 96

摘要

The hydroboration of alkenes containing representative functional groups was examined with 9-borabicyclo [3.3. l] nonane (9-BBN) in order to extend the hydroboration reaction for the preparation of functionally substituted organoboranes. Terminal alkenes containing a remote functional group are hydroborated with a remarkable regioselectivity (298% terminal), producing the corresponding stable organoboranes. 9-BBN hydroborates the ...

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