Due to their important biological properties, the preparation of heterobiaryls is an important industrial goal. The palladium-catalysed Suzuki cross-coupling reaction between heteroaryl halides and arylboronic acids provides a very efficient method for the preparation of heterobiaryl derivatives [1, 2]. On the other hand, the reverse reaction using heteroarylboronic acids and aryl halides has attracted much less attention, and most of the ...
[Martin, Anthony R.; Chartoire, Anthony; Slawin, Alexandra M.Z.; Nolan, Steven P. Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 1637 - 1643]