Tetrahedron

Base-promoted elaboration of aziridines

…, M Valacchi, L Zani, A Degl'Innocenti, G Reginato

文献索引：Mordini, Alessandro; Russo, Francesco; Valacchi, Michela; Zani, Lorenzo; Degl'Innocenti, Alessandro; Reginato, Gianna Tetrahedron, 2002 , vol. 58, # 35 p. 7153 - 7163

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被引用次数: 36

摘要

The base-promoted isomerization of aziridines to allyl amines is still an almost unknown reaction. However, the use of superbasic reagents has shown to be able to promote a regio- and stereoselective conversion of monocyclic and bicyclic sulfonyl aziridines. Moreover, the use of alkoxy substituted aziridines opens new routes to non-natural α-and β-amino acids.